有机化学 ›› 2008, Vol. 28 ›› Issue (06): 1107-1110. 上一篇    下一篇

研究简报

水相中铟促进下支链高烯丙基醇的合成

胡丽华,纪顺俊*   

  1. (苏州大学化学化工学院 苏州 215123)
  • 收稿日期:2007-07-30 修回日期:2007-11-19 发布日期:2008-06-26
  • 通讯作者: 纪顺俊

Synthesis of Branched Homoallylic Alcohols Mediated by Indium in Aqueous Medium

HU Li-Hua, JI Shun-Jun*   

  1. (<I>School of Chemistry and Chemical Engineering</i>, <I>Suzhou University</i>, <I>Suzhou</i> <i>215123</i>)
  • Received:2007-07-30 Revised:2007-11-19 Published:2008-06-26
  • Contact: JI Shun-Jun

通过铟促进下醛与2-苯基-4-溴-2-丁烯在水相中经烯丙基化反应合成一系列的支链高烯丙基醇, 产率较高, 反应条件温和.

关键词: 高烯丙基醇, 铟, 烯丙基化

Easy access to synthesize branched homoallylic alcohols was investigated. Branched homoallylic alcohols were obtained in moderate to good yields via indium-mediated allylation reactions with 1-bromo-3-phenyl-2-butene in mild condition.

Key words: indium, allylation, homoallylic alcohol