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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (11): 1762-1767. 上一篇    下一篇

研究论文

新型卟啉衍生物的合成、结构表征和电化学性质的研究

王顺      谷永红   

  1. (中国科学技术大学化学与材料科学学院 合肥 230026)
  • 收稿日期:2009-03-01 修回日期:2009-05-15 发布日期:2009-06-08
  • 通讯作者: 谷永红 E-mail:ygu01@ustc.edu.cn
  • 基金资助:

    国家级.国家自然科学基金

Synthesis, Structure Characterization of New Derivatives of Porphyrin and Study on Their Electrochemical Properties

Wang, Shun      Gu, Yonghong*   

  1. (Department of Chemistry, University of Science and Technology of China, Hefei 230026)
  • Received:2009-03-01 Revised:2009-05-15 Published:2009-06-08

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以合成的[5-(4-溴苯基)-10,15,20-三苯基卟啉]锌为底物，通Stille偶联的方法合成5-(4’-氨基-4-联苯基)-10,15,20-三苯基卟啉，[5-(4’-氨基-4-联苯基)-10,15,20-三苯基卟啉]锌配合物以及[5- (4’-甲硫基-4-联苯基)-10,15,20-三苯基卟啉]锌配合物。并用Uv,‘H NMR, IR, Ms, Fs等表征确证了该系列配合物的结构，并用循环伏安法对以上部分产物进行了电化学性质的研究.

关键词: 卟啉衍生物, 合成, Stille偶联, 结构表征, 荧光性质, 循环伏安法

Using [5-(4-bromophenyl)-10, 15, 20-triphenylporphinato]zinc(II) as the substrate, 5-(4’-amino-biphenyl-4-yl)-10,15, 20-triphenylporphyrin, [5-(4’-amino-biphenyl-4-yl)-10,15,20-triphenylporphinato]zinc(II) and [5-(4’-methylthio-biphenyl-4-yl)-10,15, 20-triphenylporphinato]zinc(II) were synthesized by Stille coupling method as a key step. The structures of all the products were characterized with Uv, ‘H NMR, IR, Ms, Fs spectra and electrochemical properties of some compounds were studied by cyclic voltammetry.

Key words: porphyrin derivative, synthesis, Stille coupling, structure characterization, fluorescence property, cyclic voltammetry