有机化学 ›› 2010, Vol. 30 ›› Issue (06): 912-917. 上一篇    下一篇

研究简报

咪唑类离子液体催化的安息香缩合反应

赵三虎*,常慧芬,李艳霞,刘素平,赵明根   

  1. 忻州师范学院化学系 忻州 034000
  • 收稿日期:2009-07-24 修回日期:2009-11-16 发布日期:2010-01-27
  • 通讯作者: 赵三虎 E-mail:zhaosh@sxu.edu.cn
  • 基金资助:

    忻州师范学院院基金([2008-79])资助项目

Benzoin Condensation Reaction Catalyzed by Imidazolium Ionic liquids

ZHAO San-Hu, CHANG Hui-Fen, LI Yan-Xia, LIU Su-Ping, ZHAO Ming-Gen   

  1. Department of Chemistry, Xinzhou Teachers University, Xinzhou 034000
  • Received:2009-07-24 Revised:2009-11-16 Published:2010-01-27
  • Contact: ZHAO San-Hu E-mail:zhaosh@sxu.edu.cn

(-羟基酮是一类重要的有机化合物, 尤其是安息香, 在化学、医药领域都有重要的应用. 介绍了一种改进的安息香合成方法, 在咪唑类离子液体氯化1-甲基-3-苄基咪唑盐的催化下, 在温和的条件下, 两分子醛发生缩合反应, 以较高的产率得到目标化合物安息香.

关键词: 安息香, 离子液体, 合成, 催化, 超声辐射

(-Hydeoxy ketones are important organic compounds, especially benzoins have important application in chemistry and pharmacy. In this paper, an improved synthesis of benzoin in mild conditions was described and benzoin condensation reactions of aldehydes catalyzed by 1-methyl-3-benzylimidazolium chloride give the corresponding products with moderate to high yields.

Key words: benzoin, ionic liquid, synthesis, catalyze, ultrasonic radiation