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有机化学
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有机化学 ›› 2010, Vol. 30 ›› Issue (10): 1468-1481. 上一篇    下一篇

综述与进展

N-杂环卡宾金属配合物的制备及其在碳-碳多重键硅氢加成反应中的新进展

厉嘉云1,2，彭家建2，李小年*,1，马磊1，白赢2，张国栋2，来国桥*,2   

  1. (1浙江工业大学环境与资源催化研究所 绿色化学合成技术国家重点实验室培育基地 杭州 310032)
    (2杭州师范大学有机硅化学及材料技术教育部重点实验室 杭州 310012)
  • 收稿日期:2010-02-24 修回日期:2010-03-23 发布日期:2010-04-27
  • 通讯作者: 厉嘉云 E-mail:tougaos@hotmail.com

Syntheses of Metal Complexes of N-Heterocyclic Carbenes and Recent Progress in Carbon-Carbon Multiple Bonds Hydrosilylation

Li Jiayun1,2 Peng Jiajian2 Li Xiaonian*,1 Ma Lei1 Bai Ying2 Zhang Guodong2 Lai Guoqiao*,2   

  1. (1 State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Resources & En-vironment Catalysis Institute, Zhejiang University of Technology, Hangzhou 310032)
    (2 Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou 310012)
  • Received:2010-02-24 Revised:2010-03-23 Published:2010-04-27

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综述了N-杂环卡宾金属配合物的制备方法, 并总结了N-杂环卡宾金属配合物在碳-碳硅氢加成反应中的新进展.

关键词: N-杂环卡宾金属配合物, 碳-碳多重键硅氢加成, 催化剂

Syntheses of N-heterocyclic carbene metal complexes and recent progresses of the metal N-heterocyclic carbene catalysts for carbon-carbon multiple bonds hydrosilylation are reviewed.

Key words: N-heterocyclic carbene metal complexe, carbon-carbon multiple bonds hydrosilylation, catalyst