有机化学 ›› 2011, Vol. 31 ›› Issue (06): 804-813. 上一篇    下一篇

综述与进展

芳香化合物氧化溴化研究进展

张国富1,3,王涌1,丁成荣*,1,刘仁华2,梁鑫淼3   

  1. (1浙江工业大学化学工程与材料学院 杭州 310014)
    (2华东理工大学药学院 上海 200237)
    (3中国科学院大连化学物理研究所 大连 116023)5. 大连:中科院大连化学物理研究所  
  • 收稿日期:2010-07-21 修回日期:2010-11-15 发布日期:2010-12-20
  • 通讯作者: 丁成荣 E-mail:dingcr2004@yahoo.com.cn

Recent Advances in Oxybromination of Aromatic Compounds

Zhang Guofu1,3,WangYong1 Ding Chen-grong*,1 Liu Renhua2 Liang Xinmiao3   

  1. (1 College of Chemical Engineering and Materials Science, Zhejiang University of Technol-ogy, Hangzhou 310014)
    (2 School of Pharmacy, East China University of Science and Technology, Shanghai 200237)
    (3 Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023)
  • Received:2010-07-21 Revised:2010-11-15 Published:2010-12-20
  • Contact: DING chengrong E-mail:dingcr2004@yahoo.com.cn

芳香化合物的氧化溴化反应是合成芳香溴化物的重要方法之一. 综述了近年来芳香化合物氧化溴化的研究进展, 主要包括化学计量的氧化溴化和催化氧化溴化等部分, 其中后者主要包括H2O2和O2作氧化剂的催化氧化溴化.

关键词: 芳香化合物, 芳香溴化物, 氧化溴化, 催化氧化, 过氧化氢, 氧气

Recent researches on the oxybromination of aromatic rings, one of the most atom-economic protocols to obtain brominated aromatic compounds, are reviewed in this paper, which includes stoichiometric and catalytic ones. Hydrogen peroxide and oxygen, the best candidates for oxidants in the catalytic oxybromination, are discussed in detail.

Key words: aromatic compound, aryl bromide, oxybromination, catalytic oxidation, hydrogen peroxide, oxygen