有机化学 ›› 2011, Vol. 31 ›› Issue (07): 973-985. 上一篇    下一篇

综述与进展

轮烷类化合物的合成方法研究进展

纪奉元,朱亮亮*   

  1. (华东理工大学精细化工研究所 结构可控先进功能材料及其制备教育部重点实验室 上海 200237)
  • 收稿日期:2010-09-27 修回日期:2010-11-16 发布日期:2010-12-29
  • 通讯作者: 朱亮亮 E-mail:zllzll@mail.ecust.edu.cn

Progress on Synthesis of Rotaxane Analogues

JI Feng-Yuan, ZHU Liang-Liang   

  1. (Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai 200237)
  • Received:2010-09-27 Revised:2010-11-16 Published:2010-12-29
  • Contact: Liang-Liang ZHU E-mail:zllzll@mail.ecust.edu.cn

轮烷类互锁分子因其多样的结构和性质, 多年来一直是超分子化学领域的一个热点. 综述了近年来轮烷类化合物的合成及制备方法, 包括用传统的模板法(引入氢键、疏水作用、静电效应、配位和离子诱导等超分子作用)制备轮烷类化合物. 除此之外, 还介绍了利用“Click”化学、“穿线-收缩”、“穿线-膨胀”、自排序组织和自由基识别等新的合成手段来制备这类化合物.

关键词: 超分子, 轮烷, 模板法

Rotaxane-based interlocked molecular system has become a hot issue in supramolecular chemistry for years, owing to its various structural architectures and performances. This tutorial review mainly focuses on the synthetic strategies of the rotaxane analogues in recent years. The traditional template-directed strategies of rotaxane preparation including the employment of the supramolecular interaction such as hydrogen bonding, hydrophobic effect, electrostatic interaction, coordination and ionic template are reviewed, respectively. Some novel synthetic methodologies, like “click” chemistry, “threading-followed-by-shrink- ing” and “threading-followed-by-swelling” protocol, self-sorting organization as well as radical recognition, are also introduced.

Key words: supramolecular, rotaxane, template-directed strategies