有机化学 ›› 2015, Vol. 35 ›› Issue (1): 39-54.DOI: 10.6023/cjoc201407026 上一篇    下一篇

综述与进展

共轭烯酸与聚乙二醇缩合反应研究进展

陈锦芳, 许孝良, 李小年   

  1. 浙江工业大学 化学工程学院 工业催化研究所 杭州 310014
  • 收稿日期:2014-07-14 修回日期:2014-09-12 发布日期:2014-09-16
  • 通讯作者: 许孝良, 李小年 E-mail:xuxiaoliang@zjut.edu.cn;xnli@zjut.edu.cn
  • 基金资助:

    浙江省自然科学基金(No. LY12B02017)、国家重点基础研究发展计划(973计划, No. 2011CB710800)资助项目.

Research Development on the Condensation Reaction of Conjugated Olefine Acid and Polyethylene Glycol

Chen Jinfang, Xu Xiaoliang, Li Xiaonian   

  1. Institute of Industrial Catalysis, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014
  • Received:2014-07-14 Revised:2014-09-12 Published:2014-09-16
  • Supported by:

    Project supported by the Zhejiang Provincial Natural Science Foundation (No. LY12B02017) and the National Basic Research Program of China (973 Program, No. 2011CB710800).

聚乙二醇不饱和酸酯是一类重要的高聚物单体, 其与其他单体接枝共聚也可合成多功能化的高分子聚合物. 主要综述了聚乙二醇与丙烯酸、甲基丙烯酸、马来酸等共轭烯酸缩合反应的研究进展, 并对其发展进行了展望.

关键词: 共轭烯酸, 聚乙二醇, 缩合反应

Unsaturated acid esters of polyethylene glycol (PEG) are important monomers for the preparation of polymers. In addition, multifunctional polymers can be synthesized by the graft copolymerization of unsaturated acid esters of PEG with other monomers. The research development of the condensation reaction of PEG with conjugated olefine acids, such as acrylic acid, methyl acrylic acid, maleic acid, etc. is reviewed, and its outlook in the future is given.

Key words: conjugated olefine acid, PEG, condensation reaction