有机化学 ›› 2015, Vol. 35 ›› Issue (12): 2487-2506.DOI: 10.6023/cjoc201506002 上一篇    下一篇

综述与进展

呋喃衍生物:一类新兴的有机半导体材料

李保林   

  1. 中国科学院大学化学与化工学院 北京 100049
  • 收稿日期:2015-06-02 修回日期:2015-07-06 发布日期:2015-08-25
  • 通讯作者: 李保林 E-mail:libl@ucas.ac.cn
  • 基金资助:

    国家自然科学基金(No. 21402194)资助项目.

Furan Derivatives: An Emerging Class of Organic Semiconductors

Li Baolin   

  1. School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049
  • Received:2015-06-02 Revised:2015-07-06 Published:2015-08-25
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21402194).

π-共轭分子广泛用于有机场效应晶体管、有机太阳能电池、染料敏化太阳能电池和有机发光二极管等领域中. 在π-共轭分子中引入呋喃环可以显著的改变分子的光学、电化学、电荷传输等性质. π-共轭呋喃衍生物由于具有载流子迁移率高、荧光量子效率高以及溶解性好等特点, 引起了国内外广泛的研究兴趣. 实验和理论研究都已证明呋喃衍生物是一类优良的半导体材料, 可以用于制得高性能的场效应晶体管、有机太阳能电池、染料敏化太阳能电池和有机发光二极管. 作者在简单介绍呋喃衍生物特点的基础上, 着重介绍了呋喃衍生物应用于制备有机场效应晶体管、有机太阳能电池、染料敏化太阳能电池和有机发光二极管等领域中的研究进展.

关键词: 呋喃, 有机半导体材料, 场效应晶体管, 有机太阳能电池, 染料敏化太阳能电池, 有机发光二极管

π-Conjugated molecules are widely used in the fields of organic field-effect transistors, organic solar cells, dye-sensitized solar cells and organic light-emitting diodes, etc. π-Conjugated furan derivatives have attracted widespread interest due to the high carrier mobility, high photoluminescent quantum efficiency and good solubility. It has been corroborated that furan derivatives are a class of good semiconducting materials by the experimental and theoretical research results. A furan ring is frequently integrated into π-conjugated molecules either by fusion with carbon π-system or by using as a π-linker, which significantly alters the photophysical, electrochemical and charge transporting properties of the π-conjugated molecules. Furan derivatives could be used to fabricate high performance organic field-effect transistors, organic solar cells, dye-sensitized solar cells and organic light-emitting diodes. In addition to a brief introduction of the characteristics of furan derivatives, the author introduced the research progress of the application of furan derivatives in the fields of organic field-effect transistors, organic solar cells, dye-sensitized solar cells and organic light-emitting diodes.

Key words: furan derivative, organic semiconducting material, organic field-effect transistor, organic solar cell, dye-sensitized solar cell, organic light-emitting diode