不同价态Mn(II, III, V)催化的烯烃环氧化反应研究进展

doi:10.6023/cjoc201604010

有机化学 ›› 2016, Vol. 36 ›› Issue (8): 1765-1778.DOI: 10.6023/cjoc201604010 上一篇下一篇

综述与进展

不同价态Mn(II, III, V)催化的烯烃环氧化反应研究进展

邹晓川^a,b, 石开云^a, 李俊^a, 王跃^a, 王存^a, 邓朝芳^a, 任彦荣^a, 谭君^a, 傅相锴^b

a 重庆第二师范学院生物与化学工程系南岸 400067;
b 西南大学化学化工学院应用化学研究所重庆市应用化学重点实验室三峡库区生态环境教育部重点实验室北碚 400715

收稿日期:2016-04-05 修回日期:2016-05-03 发布日期:2016-06-01
通讯作者: 石开云, 傅相锴 E-mail:shiky@cque.edu.cn,fxk@swu.edu.cn
基金资助:
重庆市基础与前沿研究（Nos. cstc2015jcyjA0317，cstc2013jcyjA50033）、重庆市教育委员会科学技术研究（Nos. KJ1501411，KJ131513，KJ131512）、重庆市高校创新团队研究（No. KJTD201325）、重庆第二师范学院绿色合成与分析检测重点实验室（No. 16xjpt08）、重庆第二师范学院创新团队（No. KYC-cxtd03-20141z02）资助项目.

Research Progress on Epoxidation of Olefins Catalyzed by Mn(II, III, V) in Different Valence States

Zou Xiaochuan^a,b, Shi Kaiyun^a, Li Jun^a, Wang Yue^a, Wang Cun^a, Deng Chaofang^a, Ren Yanrong^a, Tan Jun^a, Fu Xiangkai^b

a Department of Biological and Chemical Engineering, Chongqing University of Education, Nan'an 400067;
b Key Laboratory of Applied Chemistry of Chongqing Municipality, Key Laboratory of Eco-environments in Three Gorges Reservoir Region Ministry of Education, Research Institute of Applied Chemistry, College of Chemistry and Chemical Engineering, Southwest University, Beibei 400715

Received:2016-04-05 Revised:2016-05-03 Published:2016-06-01
Supported by:
Projects supported by the Basic and Frontier Research Project of Chongqing (Nos. cstc2015jcyjA0317, cstc2013jcyjA50033), the Scientific and Technological Research Program of Chongqing Municipal Education Commission (Nos. KJ1501411, KJ131513, KJ131512), the Innovation Team Building at Institutions of Higher Education in Chongqing (No. KJTD201325), the Key Laboratory of Green Synthesis and Analysis of Chongqing University of Education (No. 16xjpt08) and the Innovative Research Team in Chongqing University of Education (No. KYC-cxtd03-20141002).

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摘要/Abstract

在过去的十多年中，由过渡金属（Cr，Ni，Co，Ru，Mn）参与催化的烯烃环氧化反应受到人们的大量关注，制备的环氧化物中间体被广泛应用于医药、农药以及精细化学品的合成. 相比其它过渡金属，Mn及其配合物催化剂具有廉价、环境友好、化学稳定性高、催化效率高等优点. 综述了不同氧化价态的Mn（II，III，V）与不同N_XO_Y配体形成的催化剂，在不同的氧化剂/助催化剂参与下高效催化烯烃环氧化反应的研究现状，同时，对不同价态的Mn催化剂参与烯烃环氧化过程以及活性氧中间体如何将氧转移给烯烃的机理进行讨论.

关键词: 金属锰(II, III, V)催化剂, 配体, 环氧化, 有机聚合物/无机磷酸盐(Zr, Zn, Al, Ca), 催化机理

The epoxidation catalyzed by transition metals (Cr, Ni, Co, Ru, Mn) has been received widespread attention over the past decades, and the corresponding epoxides are widely used in the synthesis of pharmaceuticals, fine chemicals and pesticides. Compared to other transition metals, metal Mn catalyst has been widely used in organic synthesis due to its inexpensive, environment-friendly, chemical stability and high catalytic activity. This paper reviews the recent progress on epoxidation of olefins catalyzed by the catalysts which were formed by the reaction of different valence metal Mn(II, III, and V) and different N_XO_Y ligands in different oxidants/co-catalyst systems. At the same time, the Mn catalysts with different valence states are involved in the process of the epoxidation of olefins and the mechanism of how to transfer the oxygen of reactive intermediates to the olefins was discussed.

Key words: metal manganese(II, III, V) catalysts, ligands, epoxidation, organic polymer/inorganic phosphate melt (Zr, Zn, Al, Ca), catalytic mechanism

引用此文

邹晓川, 石开云, 李俊, 王跃, 王存, 邓朝芳, 任彦荣, 谭君, 傅相锴. 不同价态Mn(II, III, V)催化的烯烃环氧化反应研究进展[J]. 有机化学, 2016, 36(8): 1765-1778.

Zou Xiaochuan, Shi Kaiyun, Li Jun, Wang Yue, Wang Cun, Deng Chaofang, Ren Yanrong, Tan Jun, Fu Xiangkai. Research Progress on Epoxidation of Olefins Catalyzed by Mn(II, III, V) in Different Valence States[J]. Chin. J. Org. Chem., 2016, 36(8): 1765-1778.

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不同价态Mn(II, III, V)催化的烯烃环氧化反应研究进展

Research Progress on Epoxidation of Olefins Catalyzed by Mn(II, III, V) in Different Valence States

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