有机化学 ›› 2017, Vol. 37 ›› Issue (3): 555-565.DOI: 10.6023/cjoc201609006 上一篇    下一篇

综述与进展

纳米金属氧化物催化含氮杂环类化合物的合成研究进展

张金, 刘佳, 马养民, 程佩   

  1. 陕西科技大学化学与化工学院 教育部轻化工助剂化学与技术重点实验室 西安 710021
  • 收稿日期:2016-09-06 修回日期:2016-11-27 发布日期:2016-12-12
  • 通讯作者: 马养民,E-mail:mym63@sina.com E-mail:mym63@sina.com
  • 基金资助:

    陕西省自然科学基础研究计划(No.2014JQ2064)、陕西省教育厅重点实验室项目(No.15JS012)、陕西科技大学博士科研启动基金(No.BJ12-26)资助项目.

Progress in the Synthesis of N-Fused Heterocycles Catalyzed by Nanocrystalline Metal Oxides

Zhang Jin, Liu Jia, Ma Yangmin, Cheng Pei   

  1. Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry, College of Chemistry & Chemical Engineering, Shaanxi University of Science & Technology, Ministry of Education, Xi'an 710021
  • Received:2016-09-06 Revised:2016-11-27 Published:2016-12-12
  • Contact: 10.6023/cjoc201609006 E-mail:mym63@sina.com
  • Supported by:

    Project supported by the Natural Science Basic Research Plan in Shaanxi Province (No. 2014JQ2064), the Scientific Research Project Item for Key Laboratory of Shaanxi Provincal Education Department (No. 15JS012), and the Foundation for Young Scholars of Shaanxi University of Science & Technology (No. BJ12-26).

氮杂环化合物是杂环化合物的重要组成部分.作为许多具有生理活性的生物碱、医药化合物的基本骨架,含氮的杂环化合物的合成有巨大的应用价值.近年来,纳米金属氧化物作为一种绿色非均相的催化剂在氮杂环的构成方面有越来越广泛的应用,综述了近五年来纳米金属氧化物在催化含氮杂环化合物合成研究的新进展.

关键词: 纳米氧化物, 含氮杂环化合物, 催化剂

N-Fused heterocycles are an important class of organic compounds. As a basic scaffold of a wide variety of biologically active alkaloids and synthetic pharmaceuticals and agrochemicals, the construction methods of N-fused heterocycles have attracted much attention. Significant efforts have been devoted to the application of the nanocrystalline metal oxides as heterogeneous, efficient and environmentally friendly catalyst in organic reaction. This review provides a summary of the synthesis of the different kinds of N-fused heterocycles in recent 5 years catalyzed by the nanocrystalline metal oxides.

Key words: nanocrystalline metal oxides, N-fused heterocycles, catalyst