硼基路易斯酸-过渡金属配合物:新型双功能催化剂（英文）

doi:10.6023/cjoc201703002

有机化学 ›› 2017, Vol. 37 ›› Issue (9): 2187-2202.DOI: 10.6023/cjoc201703002 上一篇下一篇

综述与进展

硼基路易斯酸-过渡金属配合物:新型双功能催化剂（英文）

李胤午^a, 张鉴予^a, 舒思桅^b, 邵佑湘^a, 刘艳^b, 柯卓锋^a

a 中山大学材料科学与工程学院聚合物复合材料及功能材料教育部重点实验室广州 510275;
b 广东工业大学化学工程与轻工业学院广州 510006

收稿日期:2017-03-01 修回日期:2017-05-27 发布日期:2017-07-14
通讯作者: 刘艳, 柯卓锋 E-mail:yanliu@gdut.edu.cn;kezhf3@mail.sysu.edu.cn
基金资助:
国家自然科学基金（Nos.21673301，21473261，21502023）、广东省自然科学杰出青年基金（No.2015A030306027）资助项目.

Boron-Based Lewis Acid Transition Metal Complexes as Potential Bifunctional Catalysts

Li Yinwu^a, Zhang Jianyu^a, Shu Siwei^b, Shao Youxiang^a, Liu Yan^b, Ke Zhuofeng^a

a Key Laboratory for Polymeric Composite & Functional Materials of Ministry of Education, School of Materials Science & Engineering, Sun Yat-sen University, Guangzhou 510275;
b School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006

Received:2017-03-01 Revised:2017-05-27 Published:2017-07-14
Contact: 10.6023/cjoc201703002 E-mail:yanliu@gdut.edu.cn;kezhf3@mail.sysu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21673301, 21473261, 21502023) and the Guangdong Natural Science Funds for Distinguished Young Scholar (No. 2015A030306027).

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摘要/Abstract

路易斯酸-过渡金属（LA-TM）配合物作为一种新型的双功能催化剂崭露头角.有别于传统的过渡金属双功能催化剂，LA-TM催化剂另辟蹊跷，用路易斯酸功能位点作为电子受体，过渡金属作为电子给体，进行新型的双功能催化.近期，LA-TM配合物迅速发展.依据其键合特点，对硼基LA-TM配合物进行综述，包括sp³杂化、sp²杂化和sp杂化的硼基LA-TM配合物，并归纳了其在LA-TM催化方面的潜在应用，包括H-H/E-H/E-E键活化、氢化、硅氢化和转移脱氢化等等.本综述有望将为开拓LA-TM双功能催化的新领域提供有价值的信息.

关键词: 路易斯酸, 过渡金属, 双功能催化, 硼, 活化, 加氢, 脱氢

Lewis acid-transition metal (LA-TM) complexes, with the LA site functions as an electron acceptor and the TM center functions as an electron donor, have been emerging as a new type of bifunctional catalysts lately, different from traditional transition metal bifunctional catalysts. Due to their rapid developments recently, the boron-based LA-TM complexes, which are divided into three major types, the sp³, sp², and sp boron-based complexes, are reviewed in this paper according to their binding features. Reactions promoted by this new type of LA-TM bifunctional catalysts have been surveyed, including migration reactions, activation of H-H/E-H/E-E bonds, hydrogenations, hydrosilylations, and transfer dehydrogenation reactions etc. This overview of boron-based LA-TM complexes could provide valuable information to explore the new horizon in LA-TM bifunctional catalysis.

Key words: Lewis acid, transition metal, bifunctional catalysis, boron, activation, hydrogenation, dehydrogenation

引用此文

李胤午, 张鉴予, 舒思桅, 邵佑湘, 刘艳, 柯卓锋. 硼基路易斯酸-过渡金属配合物:新型双功能催化剂（英文）[J]. 有机化学, 2017, 37(9): 2187-2202.

Li Yinwu, Zhang Jianyu, Shu Siwei, Shao Youxiang, Liu Yan, Ke Zhuofeng. Boron-Based Lewis Acid Transition Metal Complexes as Potential Bifunctional Catalysts[J]. Chin. J. Org. Chem., 2017, 37(9): 2187-2202.

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硼基路易斯酸-过渡金属配合物:新型双功能催化剂（英文）

Boron-Based Lewis Acid Transition Metal Complexes as Potential Bifunctional Catalysts

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