有机化学 ›› 2018, Vol. 38 ›› Issue (8): 1885-1896.DOI: 10.6023/cjoc201804031 上一篇    下一篇

所属专题: 碳氢活化合辑2018-2019 元素有机化学合辑2018-2019

综述与进展

碱土金属促进氢官能团化反应的研究进展

李园园a,b,d, 程玉华a, 单春晖c, 张敬e, 徐冬冬c, 白若鹏c, 屈凌波d, 蓝宇c,d   

  1. a 重庆第二师范学院生物与化学工程学院 重庆 400067;
    b 重庆第二师范学院脂质资源与儿童日化品协同创新中心 重庆 400067;
    c 重庆大学化学化工学院 重庆 401331;
    d 郑州大学化学与分子工程学院 郑州 450006;
    e 济宁学院化学与化工系 济宁 272001
  • 收稿日期:2018-04-16 修回日期:2018-05-11 发布日期:2018-05-17
  • 通讯作者: 蓝宇 E-mail:lanyu@cqu.edu.cn
  • 基金资助:

    重庆市科委基金(基础研究与前沿探索)(No.cstc2017jcyjAX0371)、重庆第二师范学院科技协同创新平台建设(No.2017XJPT01)、重庆第二师范学院校级重点项目(No.KY201704A)及重庆第二师范学院博士启动基金(No.2017BSRC001)资助项目.

Recent Advances in Alkaline-Earth-Metal-Catalyzed Hydrofunctionalization Reactions

Li Yuanyuana,b,d, Cheng Yuhuaa, Shan Chunhuic, Zhang Jinge, Xu Dongdongc, Bai Ruopengc, Qu Lingbod, Lan Yuc,d   

  1. a College of Biological and Chemical Engineering, Chongqing University of Education, Chongqing 400067;
    b Cooperative Innovation Center of Lipid Resources and Children's Daily Chemicals, Chongqing University of Education, Chongqing 400067;
    c School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331;
    d College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450006;
    e Department of Chemistry and Chemical Engineering, Jining University, Jining 272001
  • Received:2018-04-16 Revised:2018-05-11 Published:2018-05-17
  • Contact: 10.6023/cjoc201804031 E-mail:lanyu@cqu.edu.cn
  • Supported by:

    Project supported by the Basic and Frontier Research Project of Chongqing Science and Technology Commission (No. cstc2017jcyjAX0371), the Project of Science and Technology Collaborative Innovation Platform Construction of Chongqing University of Education (No. 2017XJPT01), the University-level Key Projects of Chongqing University of Education (No. KY201704A), and the Scientific Research Foundation of Chongqing University of Education (No. 2017BSRC001).

碱土金属及其化合物由于其储量丰富、成本低而被应用于催化反应中.近年来,碱土金属催化脱氢偶联反应、硼氢化反应、氢膦化反应、氢胺化反应以及氢化硅烷化反应等被关注和研究,无论在实验还是原理上都取得了大量的进展.针对这类反应及其机理进行总结归纳,从而完整描绘了碱土金属在氢化或脱氢反应中起到的作用.这类反应中,往往都涉及到碱土金属氢化物作为活性物种,反应过程中都要经历碱土金属氢共价键的形成和断裂.通过对这些反应的分类和讨论,从整体上认识了这类反应的反应条件和反应历程,为今后设计碱土金属催化剂和同类型反应的催化循环提供了指导.

关键词: 碱土金属催化剂, 氢官能团化反应, 机理研究, 研究进展

Alkaline-earth-metal compounds have been widely concerned due to its abundant reserve and the low-cost. In recent years, alkaline-earth-metal catalysis has achieved great progress in dehydrocoupling, hydroboration, hydrophosphination, hydroamination, hydrosilylation reactions experimentally and therotically. These types of reaction and catalytic mechanism, leading to indentify the role of alkaline-earth-metal in hydrogenation and dehydrogenation reaction are summarized. These reactions, in which the metal-hydride act as active species, generally undergo the reaction pathway involving the cleavage and formation of the metal-hydride covalent bond. The reaction features and mechanisms are generally recognized accrossing to the classification and discussion of these reactions, which would provide guidance for further development of alkaline-earth-metal catalysis.

Key words: alkaline-earth-metals catalyst, hydrofunctionalization reaction, mechanism study, recent advance