有机化学 ›› 2018, Vol. 38 ›› Issue (12): 3143-3154.DOI: 10.6023/cjoc201804006 上一篇    下一篇

综述与进展

氟化富勒烯的结构、性质及其应用研究进展

王宇飞a, 郑丽萍a, 李靖靖a, 刘超b, 姚建华b   

  1. a 郑州工程技术学院化工食品学院 郑州 450044;
    b 中国科学院上海有机化学研究所 上海 200032
  • 收稿日期:2018-04-04 修回日期:2018-06-11 发布日期:2018-08-14
  • 通讯作者: 姚建华 E-mail:yaojh@sioc.ac.cn
  • 基金资助:

    河南省科技开放合作计划(No.172106000067)资助项目.

Progress in the Structures, Characteristics and Applications of Fluorofullerenes

Wang Yufeia, Zheng Lipinga, Li Jingjinga, Liu Chaob, Yao Jianhuab   

  1. a School of Chemical Engineering and Food Science, Zhengzhou Institute of Technology, Zhengzhou 450044;
    b Shanghai institute of Organnic Chemistry, Chinese Academy of Sciences, Shanghai 200032
  • Received:2018-04-04 Revised:2018-06-11 Published:2018-08-14
  • Contact: 10.6023/cjoc201804006 E-mail:yaojh@sioc.ac.cn
  • Supported by:

    Project supported by the Henan Science and Technology Open Cooperation Project of Henan Prince (No. 172106000067)

氟化富勒烯因其独特的结构引起了研究者们持续而广泛的关注.在介绍氟化富勒烯的结构和电子特性的基础上,总结了其在金刚石、硅、石墨烯等材料的表面掺杂,以及有机发光二极管等电子器件的p型掺杂等领域的应用.最后,介绍了氟化富勒烯在其他领域中的最新应用,并对氟化富勒烯材料的发展趋势和前景进行了展望.

关键词: 富勒烯, 氟化富勒烯, 电子特性, 前驱体, 掺杂剂

Fluofullerenes have attracted extensive attention due to their unique structures. The structures and the electronic properties of various fluofullerenes are mainly introduced, and then their applications are summarized in the field of precursors of functional fullerene derivatives, surface doping of diamond, dilicon, and graphene, and bulk p-doping of organic semiconductors in electronic devices. Furthermore, this review introduces the progress of new research on their application in other field, and gives the outlook for research trend and prospect of fluofullerenes materials.

Key words: fullerenes, fluorofullerenes, electronic properties, precursors, dopant