基于I2催化的C-H键功能团化的研究进展

doi:10.6023/cjoc201902001

摘要/Abstract

杂环化合物在医药、精细化工等领域具有广泛的应用价值.因此，开发高效的杂环构筑策略在有机合成中仍然具有强大的吸引力.近年来，基于I₂催化的直接C-H功能团化反应已发展成为构筑杂环化合物的重要方法之一.在此，按化合物的成键类型（C-C、C-N/O/S），综述近年来该领域的重要研究进展，并做总结与展望.

关键词: 碘催化, 碳氢键活化, 杂环化合物

Heterocyclic compounds are widely applied in medicine, fine chemical engineering and the related industrial fields. Consequently, the development of efficient strategies for heterocycle constructions continues to be of great appeal in organic synthesis. In recent years, the I₂-catalyzed direct C-H bond functionalizations have emerged as one of the most efficient synthetic protocols to construct diverse heterocycles. In this review, the recent advances in I₂-catalyzed C-H bond functionalizations by the types of C-C and C-N/O/S bond formations are summarized, and an outlook of this research filed is given.

Key words: I₂-catalysis, C-H bond activation, heterocycles

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施兆江, 王连会, 崔秀灵. 基于I₂催化的C-H键功能团化的研究进展[J]. 有机化学, 2019, 39(6): 1596-1612.

Shi Zhaojiang, Wang Lianhui, Cui Xiuling. Recent Advances in the I₂-Catalyzed C-H Bond Functionalizations[J]. Chin. J. Org. Chem., 2019, 39(6): 1596-1612.

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基于I₂催化的C-H键功能团化的研究进展

Recent Advances in the I₂-Catalyzed C-H Bond Functionalizations

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