有机化学 ›› 2024, Vol. 44 ›› Issue (4): 1181-1196.DOI: 10.6023/cjoc202308003 上一篇    下一篇

综述与进展

阴离子-π相互作用研究进展

张晓, 胡密霞, 杜艳青, 梁凤英, 张笑迎, 额尔敦*()   

  1. 内蒙古医科大学药学院 呼和浩特 010110
  • 收稿日期:2023-08-04 修回日期:2023-11-06 发布日期:2023-11-23
  • 基金资助:
    国家自然科学基金(21961026); 蒙药学一流学科建设(国际合作与交流项目); 蒙药学一流学科建设(MYYXTGJ202304)

Research Progress on Anion-π Interactions

Xiao Zhang, Mixia Hu, Yanqing Du, Fengying Liang, Xiaoying Zhang, Chaolu Eerdun()   

  1. College of Pharmacy, Inner Mongolia Medical University, Hohhot 010110
  • Received:2023-08-04 Revised:2023-11-06 Published:2023-11-23
  • Contact: E-mail: 20030091@immu.edu.cn
  • Supported by:
    National Natural Science Foundation of China(21961026); Construction of First-class Disciplines in Mongolian Pharmacy (International Cooperation and Exchange Programme); Construction of First-class Disciplines in Mongolian Pharmacy(MYYXTGJ202304)

阴离子-π相互作用是主客体化学中的一种非共价引力相互作用. 通常, 芳香族π-系统被认为是富电子的, 可能与负电荷体系间存在排斥作用. 因此, 看似违反常理的阴离子-π相互作用, 自其首次被报道就受到了高度关注, 并迅速在分子识别、催化、自组装、聚集诱导发光材料和新型阴离子受体设计合成等领域展现出了广阔而重要的应用前景. 综述了近10年阴离子-π相互作用在理论计算研究、催化、自组装、受体设计与合成、聚集诱导发光等领域的研究进展, 并对于阴离子-π相互作用在超分子化学领域中的研究与应用进行展望, 为超分子化学研究提供参考.

关键词: 阴离子-π相互作用, 超分子化学, 受体合成, 识别

Anion-π interaction is a non-covalent interaction in host-guest chemistry. In general, aromatic π-systems are regarded as electron rich and may have repulsive interactions with negatively charged systems. Therefore, the anion-π interaction, which seems counterintuitive, has attracted remarkable attention since it was first reported. And surprisingly, it has shown broad and significant potential applications in various fields, including molecular recognition, catalysis, self-assembly, aggregation-induced luminescent materials, and the design and synthesis of novel anionic receptors. This review focuses on the research progress of anion-π interactions in the fields of theoretical studies, catalysis, self-assembly, receptor design and synthesis, and aggregation-induced luminescence in the last decade. Finally, the research and application prospects of anion-π interactions in the field of supramolecular chemistry will be provided.

Key words: anion-π interactions, supramolecular chemistry, receptor synthesis, recognition