三配位芳基硼自由基: 从分子设计到电子结构调控

doi:10.6023/cjoc202604051

有机化学 ›› 2026, Vol. 46 ›› Issue (9): 3414-3430.DOI: 10.6023/cjoc202604051 上一篇下一篇

综述与进展

三配位芳基硼自由基: 从分子设计到电子结构调控

高浩雨^a, 武完瑾^a, 吴莎莎^a, 刘鑫宇^a, 何昊远^a, 席佳璐^a, 李子欣^a, 刘艳艳^a, 韩冰^a, 何曼曼^a^,^*(), Laurent Maron^a^,^c^,^d, 赵征^b^,^*(), 刘立杰^a^,^*()

^a 河南农业大学化学与材料学院中国郑州 450002
^b 香港中文大学(深圳)理工学院广东省聚集体科学基础研究中心中国深圳 518172
^c 河南农业大学农学院中国郑州 450002
^d 图卢兹第三大学纳米物体物理与化学实验室国家应用科学研究所法国图卢兹 31077

收稿日期:2026-04-29 修回日期:2026-06-03 发布日期:2026-07-14
基金资助:
国家自然科学基金(22305070); 河南省科技攻关项目(252102410008); 河南省自然科学基金(242300420554); 中国博士后基金(2023T160197); 中国博士后基金(2022M711061); 河南省“科技副总”(HNFZ20240019)

Tricoordinate Arylboron Radicals: From Molecular Design to Electronic Structure Modulation

Haoyu Gao^a, Wanjin Wu^a, Shasha Wu^a, Xinyu Liu^a, Haoyuan He^a, Jialu Xi^a, Zixin Li^a, Yanyan Liu^a, Bing Han^a, Manman He^a^,^*(), Laurent Maron^a^,^c^,^d, Zheng Zhao^b^,^*(), Lijie Liu^a^,^*()

^a College of Chemstry and Materials, Henan Agricultural University, Zhengzhou 450002, China
^b Guangdong Basic Research Center of Excellence for Aggregate Science, School of Science and Engineering, The Chinese University of Hong Kong (Shenzhen), Shenzhen 518172, China
^c College of Agriculture, Henan Agricultural University, Zhengzhou 450002, China
^d Laboratory of Physics and Chemistry of Nano-Objects, Centre National de la Recherche Scientifique & Institut National des Sciences Appliquées, Université Toulouse III-Paul Sabatier, Toulouse 31077, France

Received:2026-04-29 Revised:2026-06-03 Published:2026-07-14
Contact:
^* E-mail: zhaozheng@cuhk.edu.cn;
lijieliu@henau.edu.cn;
mmanhe@163.com
About author:
Dedicated to the 100th anniversary of the birth of Professor Xikui Jiang.
Supported by:
National Natural Science Foundation of China(22305070); Henan Provincial Science and Technology Key Research and Development Program(252102410008); Natural Science Foundation of Henan Province(242300420554); China Postdoctoral Science Foundation(2023T160197); China Postdoctoral Science Foundation(2022M711061); “Deputy General Manager of Technology? of Henan Province(HNFZ20240019)

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摘要/Abstract

系统综述三配位芳基硼自由基的最新进展, 以电荷类型为主线, 依次梳理硼阴离子自由基、中性自由基与阳离子自由基的发展历程、分子设计策略、结构特征与电子性质. 系统总结了大位阻取代基、共轭骨架、卡宾配体及刚性环结构对自由基稳定性、自旋分布、单重态-三重态能隙与氧化还原行为的调控机制, 归纳结构-性能关系, 并对该领域未来的发展趋势与关键挑战进行展望, 以期为有机硼开壳层体系的分子精准设计与功能应用提供理论依据与设计指导.

关键词: 三配位芳基硼化合物, 芳基硼自由基, 自由基电子结构

This review systematically summarizes recent advances in tricoordinate arylboron radicals, organized according to charge states. The development of boron-centered anionic, neutral, and cationic radicals is discussed in sequence, with emphasis on their molecular design strategies, structural characteristics, and electronic properties. Particular attention is devoted to the roles of bulky substituents, extended π-conjugated frameworks, carbene ligands, and rigid cyclic architectures in governing radical stability, spin distribution, singlet-triplet energy gaps, and redox behavior. The structure-property relationships underlying these systems are critically analyzed, and future perspectives in this rapidly evolving field are outlined. This review aims to provide useful guidelines for the rational design and functional applications of open-shell organo- boron compounds.

Key words: tricoordinate arylboron compound, arylboron radicals, radical electronic structure

引用此文

高浩雨, 武完瑾, 吴莎莎, 刘鑫宇, 何昊远, 席佳璐, 李子欣, 刘艳艳, 韩冰, 何曼曼, Laurent Maron, 赵征, 刘立杰. 三配位芳基硼自由基: 从分子设计到电子结构调控[J]. 有机化学, 2026, 46(9): 3414-3430.

Haoyu Gao, Wanjin Wu, Shasha Wu, Xinyu Liu, Haoyuan He, Jialu Xi, Zixin Li, Yanyan Liu, Bing Han, Manman He, Laurent Maron, Zheng Zhao, Lijie Liu. Tricoordinate Arylboron Radicals: From Molecular Design to Electronic Structure Modulation[J]. Chinese Journal of Organic Chemistry, 2026, 46(9): 3414-3430.

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图/表 22

Figure 1. Tricoordinate arylboron radical molecular systems

Figure 7. Structures of 20~23

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三配位芳基硼自由基: 从分子设计到电子结构调控

Tricoordinate Arylboron Radicals: From Molecular Design to Electronic Structure Modulation

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