Synthesis and Characterization of a Novel High Nitrogen Energetic Compound 5-((5-Nitro-2H-tetrazol-2-yl)methyl)-1H-tetrazol-1-ol

doi:10.6023/cjoc201407044

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (1): 236-240.DOI: 10.6023/cjoc201407044 Previous Articles Next Articles

Notes

一种新型高氮含能化合物5-((5-硝基-2H-四唑-2-基)甲基)-1H-四唑-1-醇的合成与表征

居平文, 凌亦飞, 王桂香, 罗军

南京理工大学化工学院南京 210094

收稿日期:2014-07-29 修回日期:2014-09-01 发布日期:2014-09-16
通讯作者: 罗军 E-mail:luojun@njust.edu.cn

Synthesis and Characterization of a Novel High Nitrogen Energetic Compound 5-((5-Nitro-2H-tetrazol-2-yl)methyl)-1H-tetrazol-1-ol

Ju Pingwen, Ling Yifei, Wang Guixiang, Luo Jun

School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094

Received:2014-07-29 Revised:2014-09-01 Published:2014-09-16

1. Synthesis and Characterization of a Novel High Nitrogen Energetic Compound 5-((5-Nitro-2H-tetrazol-2-yl)methyl)-1H-tetrazol-1-ol.PDF(352KB)

Abstract

Using 5-aminotetrazole as starting material, a novel high nitrogen energetic compound 5-((5-nitro-2H-tetrazol-2- yl)methyl)-1H-tetrazol-1-ol was synthesized with a total yield of 19% via diazotization-nitration, alkylation, oximation, diazotization-chlorination, azidation and cyclization. It was characterized by NMR, MS, IR and elemental analysis. The crystal structure of this compound was determined by X-ray single crystal diffraction analysis. The results indicated that it belonged to monoclinic system with space group P2(1), and the crystal parameters were a=3.3619(11) Å, b=9.3910(19) Å, c=8.2060(16) Å, β=101.44(3)°, Z=2, D_c=1.748 g·cm^-3, μ=0.153 mm^-1, F(000)=216. The thermal properties were studied by differential scanning calorimeter (DSC) and thermogravimetric (TG) analyzer analyses, which showed that the decomposition temperature of target compound was 202.25 ℃, and the mass loss due to overall reaction (130～320 ℃) was 78.6%. The detonation velocity and detonation pressure of this compound calculated by Kamlet-Jacobs formula are 8500 m·s^-1 and 31.53 Gpa, respectively.

Key words: high-nitrogen energetic compound, tetrazole, synthesis, characterization

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Ju Pingwen, Ling Yifei, Wang Guixiang, Luo Jun. Synthesis and Characterization of a Novel High Nitrogen Energetic Compound 5-((5-Nitro-2H-tetrazol-2-yl)methyl)-1H-tetrazol-1-ol[J]. Chin. J. Org. Chem., 2015, 35(1): 236-240.

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一种新型高氮含能化合物5-((5-硝基-2H-四唑-2-基)甲基)-1H-四唑-1-醇的合成与表征

Synthesis and Characterization of a Novel High Nitrogen Energetic Compound 5-((5-Nitro-2H-tetrazol-2-yl)methyl)-1H-tetrazol-1-ol

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