Synthesis and Properties of the Fused Aza-polynitrocyclic Compounds

doi:10.6023/cjoc201512024

Abstract

Fused aza-polycyclic structures play an important role in the synthesis of energetic compounds and the presence of NNO₂ groups renders them a rich source of energy. Currently, fused aza-polynitrocyclic compounds have gained considerable prominence as novel energetic compounds. This review focuses on the synthesis of various ring skeletons of the aza-bicyclic, aza-polycyclic and aza-propellane-derivatized energetic compounds as well as the studies of N-nitration, physicochemistry and detonation properties. The synthesis of pentaaza[3.3.3]propellane and hexaaza[3.3.3]propellane is highlighted and N-nitration explorations of these high-strained unstable skeletons are discussed in details.

Key words: energetic compounds, fused aza-polycyclic structure, synthesis, N-nitration, properties

Cite this article

Zhang Junlin, Xiao Chuan, Zhai Lianjie, Wang Xijie, Bi Fuqiang, Wang Bozhou. Synthesis and Properties of the Fused Aza-polynitrocyclic Compounds[J]. Chin. J. Org. Chem., 2016, 36(6): 1197-1207.

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