Recent Advances in Transition Metal-Catalyzed Synthesis of Guanidines

doi:10.6023/cjoc201604036

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (9): 1985-1993.DOI: 10.6023/cjoc201604036 Previous Articles Next Articles

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过渡金属催化合成胍类衍生物研究进展

徐树英^a, 陈小佳^b, 黎吉辉^a, 许文茸^a, 张玉苍^a

a 海南大学材料与化工学院海口 570228;
b 海南省产品质量监督检验所海口 570003

收稿日期:2016-04-18 修回日期:2016-05-16 发布日期:2016-06-20
通讯作者: 黎吉辉, 张玉苍 E-mail:lijihui@hainu.edu.cn;zhangyucang88@163.com
基金资助:
海南省自然科学基金（Nos.20162015，20152027）、海南省国际科技合作专项（No.KJHZ2014-02）、教育部高等学校博士学科点专项科研基金（No.20134601110004）资助项目.

Recent Advances in Transition Metal-Catalyzed Synthesis of Guanidines

Xu Shuying^a, Chen Xiaojia^b, Li Jihui^a, Xu Wenrong^a, Zhang Yucang^a

a College of Materials and Chemical Engineering, Hainan University, Haikou 570228;
b Products Quality Supervision and Testing Institute of Hainan Province, Haikou 570003

Received:2016-04-18 Revised:2016-05-16 Published:2016-06-20
Supported by:
Project supported by the Natural Science Fundation of Hainan Province (Nos.20162015, 20152027), the Hainan Province International Science and Technology Specific (No.KJHZ2014-02) and the Research Fund for the Doctoral Program of Higher Education of China (No.20134601110004).

Guanidines are a unique class of tri-nitrogen compounds having various bioactivities, which are wildly presented in natural products and drug molecules, and they are wildly used in pharmacy and pesticide fields. Moreover, they have high application value in organic synthesis and functional materials. The synthesis of guanidines has received much attention due to their unique structures and widespread application value. Recently, lots of new synthetic methods of guanidines, especially the synthetic methods based on highly efficient transition metal-catalyzed reactions, have been developed. The recent progress in transition metal-catalyzed reactions developed for the synthesis of guanidines in the past twenty years is summarized. The synthetic methods for various guanidines are introduced comprehensively, and the characteristics and disadvantages of these methods are also discussed, thus it may be helpful for the research on transition metal-catalyzed synthesis of guanidines.

Key words: transition metal-catalyzed, C-N formation reaction, guanidines, synthetic method

Cite this article

Xu Shuying, Chen Xiaojia, Li Jihui, Xu Wenrong, Zhang Yucang. Recent Advances in Transition Metal-Catalyzed Synthesis of Guanidines[J]. Chin. J. Org. Chem., 2016, 36(9): 1985-1993.

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过渡金属催化合成胍类衍生物研究进展

Recent Advances in Transition Metal-Catalyzed Synthesis of Guanidines

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