Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (6): 1423-1436.DOI: 10.6023/cjoc202002035 Previous Articles     Next Articles

镍催化C—C键活化反应研究进展

代洪雪, 吴芬, 白大昌   

  1. 河南师范大学化学化工学院 河南新乡 453007
  • 收稿日期:2020-02-25 修回日期:2020-04-03 发布日期:2020-04-13
  • 通讯作者: 白大昌 E-mail:baidachang@htu.edu.cn
  • 基金资助:
    国家自然科学基金(No.21801067)、河南省高等学校重点科研项目计划(No.18A150010)及河南师范大学启动经费(No.qd17108,2019QK01)资助项目.

Recent Advances in Ni-Catalyzed C—C Bond Activation Reactions

Dai Hongxue, Wu Fen, Bai Dachang   

  1. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007
  • Received:2020-02-25 Revised:2020-04-03 Published:2020-04-13
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21801067), the Natural Science Research Program of Education Department of Henan Province (No. 18A150010) and the Start-Up Fund from Henan Normal University (Nos. qd17108, 2019QK01).

Transition-metal catalyzed C-C bond cleavage reaction is one of the most challenge topics, and has drawn considerable attention in recent years. This process has not only emerged as a useful strategy for syntheses of complex molecular skeletons, but also satisfied atom economy. Compared to the noble transition metals catalysis such as Rh, Pd and Ir, the nickel catalysis offered a more cost effective option and exhibited unique activity or selectivity. This recent advances on the Ni-catalyzed C-C bond activations are summarized.

Key words: nickel, C-C bond activation, transition-metal