Chinese Journal of Organic Chemistry ›› 2022, Vol. 42 ›› Issue (2): 471-486.DOI: 10.6023/cjoc202107065 Previous Articles     Next Articles



黄卫春, 丁欣宇*(), 訾由*()   

  1. 南通大学化学化工学院 江苏南通 226019
  • 收稿日期:2021-07-31 修回日期:2021-09-15 发布日期:2022-02-24
  • 通讯作者: 丁欣宇, 訾由
  • 基金资助:
    国家自然科学青年基金(61805147); 南通大学大型仪器设备开放基金(KFJN2112); 南通大学大型仪器设备开放基金(KFJN2119); 南通大学大型仪器设备开放基金(KFJN2127); 江苏省研究生科研与实践创新计划(SJCX21_1450)

Research Progress of Vinyl/Aryl Phosphonium Salts in Organic Synthesis

Weichun Huang, Xinyu Ding(), You Zi()   

  1. School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019
  • Received:2021-07-31 Revised:2021-09-15 Published:2022-02-24
  • Contact: Xinyu Ding, You Zi
  • Supported by:
    National Natural Science Foundation of China(61805147); Large Instruments Open Foundation of Nantong University(KFJN2112); Large Instruments Open Foundation of Nantong University(KFJN2119); Large Instruments Open Foundation of Nantong University(KFJN2127); Postgraduate Research & Practice Innovation Program of Jiangsu Province(SJCX21_1450)

Phosphines have attracted much attention as efficient ligands, catalysts or stoichiometric reductants in organic synthesis. However, the application of phosphonium salts, as a kind of important derivatives of phosphines, has focused on Wittig reaction, Staudinger reaction or other reactions as intermediates. With the rapid development of new methods, the introdcution of vinyl/aryl groups not only makes a considerable progress in the applications of vinyl/aryl phosphonium salts, but provides novel strategies for the synthesis of bioactive or pharmaceutical molecules. The review is summarized based on the types of phosphonium salts and reactions to construct vinyl/aryl groups in recent years.

Key words: vinyl phosphonium salt, aryl phosphonium salt, organic synthesis