Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (11): 3777-3793.DOI: 10.6023/cjoc202003070 Previous Articles     Next Articles

Special Issue: 有机光催化虚拟合辑 创刊四十周年专辑


徐子悦, 罗驿, 王辉, 张丹维, 黎占亭   

  1. 复旦大学化学系 上海 200438
  • 收稿日期:2020-03-31 修回日期:2020-04-22 发布日期:2020-04-30
  • 通讯作者: 张丹维, 黎占亭;
  • 基金资助:

Porous Organic Polymers as Heterogeneous Catalysts for Visible Light-Induced Organic Transformations

Xu Zi-Yue, Luo Yi, Wang Hui, Zhang Dan-Wei, Li Zhan-Ting   

  1. Department of Chemistry, Fudan University, Shanghai 200438
  • Received:2020-03-31 Revised:2020-04-22 Published:2020-04-30
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Nos. 21890732, 21890730, 21921003).

The recent applications of porous organic polymers (POPs) as heterogeneous catalysts for visible light-induced organic transformations are summarized. POPs are constructed from conjugated organic monomers, having the features of convenient synthesis and characterization, high stability for quick recovery and reuse, structural diversity as well as high modifiability. POPs possess rigid conjugated frameworks, relatively large surface areas, tunable porosity and typically insoluble in water or organic solvents, and thus ideal platforms for the development of heterogeneous catalysts. Through incorporating conjugated sensitizer units into the backbones or attaching the sensitizers to the backbone linkers, POPs can be developed as efficient heterogeneous photocatalysts for visible light-induced organic transformations. Due to their high stability and insolubility, POP catalysts can be easily recovered through filtration or centrifugation and recycled. POP-based photocatalysis combines visible light utility and catalyst recycling and thus represents a green and sustainable technique.

Key words: porous organic polymer, photocatalysis, heterogeneous catalysis, organic transformation, sustainability, green chemistry