Addition reaction of difluorocarbene with olefins induced by Tea-CO2 laser

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Chin. J. Org. Chem. ›› 1988, Vol. 8 ›› Issue (1): 48-50. Previous Articles Next Articles

激光引发二氟卡宾与烯烃的反应

史济良;王龙根;姚介兴

中国科学院上海有机化学研究所

发布日期:1988-02-25

Addition reaction of difluorocarbene with olefins induced by Tea-CO2 laser

SHI JILIANG;WANG LONGGEN;YAO JIEXING

Published:1988-02-25

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Abstract

gem-Difluorocyclopropanes were obtained in the reaction of CF2HCl (I) with olefins induced by TEA-CO2 laser. Thus, cyclopropanes II (R = H, Me) were obtained from reaction of Me2C:CR2 with I.

Key words: METHANE P, CHLOROHYDROCARBON, ALKENE, BUTENE, CYCLOPROPANE P, CARBENE, IMPULSE LASER, CO2 LASER, TETRAFLUORO ETHYLENE, FLUOROHYDROCARBON, ADDITION REACTION, LASER CHEMISTRY, LASER APPLICATION

CLC Number:

O621

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SHI JILIANG;WANG LONGGEN;YAO JIEXING. Addition reaction of difluorocarbene with olefins induced by Tea-CO2 laser[J]. Chin. J. Org. Chem., 1988, 8(1): 48-50.

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激光引发二氟卡宾与烯烃的反应

Addition reaction of difluorocarbene with olefins induced by Tea-CO2 laser

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