Chin. J. Org. Chem. ›› 1993, Vol. 13 ›› Issue (3): 286-288. Previous Articles     Next Articles

Original Articles

氧翁化合物的结构测定及其与稳定化磷叶立德的反应

LU LING;CHANG RONG-CHI;CHU KUAN-PO;LIN SHENG-WUN   

  1. 中央研究院化学研究所.台湾
  • 发布日期:1993-06-25

The structural determination of the ozonides and their reaction with sta-billzed phosphorus ylides

LU LING;CHANG RONG-CHI;CHU KUAN-PO;LIN SHENG-WUN   

  • Published:1993-06-25

Ozonides, prepared by ozonolysis of alkenes, e.g., I, reacted with stabilized phosphorus ylides to give the a,b-unsatd. carbonyl compounds e.g. II, in high yield. The Z/E ratio is dependent on the substituent of the ozonide. Their possible mechanism was described.

Key words: PHOSPHINE, WITTIG REACTION, CARBONYL COMPOUNDS, OXONIUM SALTS, PHOSPHORUS COMPOUNDS

CLC Number: