Syntheses and studies of open chain analogues of cryptands with nitrogen or carbon as central atom

Abstract

Ten open chain analogues with nitrogen or carbon as central atom (1a～e, 2a～e) were synthesized through O-alkylation of trithanolamine, pentaerythritol and 4-hydroxyantipyrine and S-alkylation of 2-mercaptobenzimidazole and 2-mercaptobenzothiazole with pentaerythrityltetrabromide. Their activities as ion transport carrier of Ag(I) in liquid membrane (CHCl~3) have been studied. It has been found that compounds 1a～e have good transport activity for Ag(I) .

Key words: SYNTHESIS, ALKYLATION, MIGRATION (CHEMICAL), ION CARRIER

CLC Number:

O621

Cite this article

LI QIWAN;LIU FUCHU. Syntheses and studies of open chain analogues of cryptands with nitrogen or carbon as central atom[J]. Chin. J. Org. Chem., 1995, 15(4): 360-364.

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含氮或碳中心原子的窝穴体开链类似物的合成与研究