Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (4): 370-375. Previous Articles     Next Articles

Original Articles

全氟丁基取代烯烃的制备及其硼氢化反应

荣国斌   

  1. 华东理工大学化学系
  • 发布日期:1995-08-25

The preparation and hydrobration reaction of perfluorobuty substituted alkenes

RONG GUOBIN   

  • Published:1995-08-25

Addition of perfluorobutyl iodide to C-C multiple bond is efficiently achieved by Na~2S~2O~4 in phase transfer of ultrasonic irradiation condition . The perfluorobutyl alkenes are produce from the β-iodoperfluorobutyl alkanes by elimination of hydrogen iodide or from β-iodoperfluorobutyl alkenes by deiodoreduction. The gydrovoration reaction of perfluorovutyl alkenes were also studied.

Key words: SYNTHESIS, HYDROBORATION, PERFLUOROOLEFINE

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