Lauryl sulfate complexes and their application to electron- transfer catalyst

Abstract

Three polyalkylviologen-lauryl sulfate complexes (PRV-LS) were prepared and their redox behaviors were studied by UV and EPR method. The reduction of azobenzene medi-ated by these complexes was investigated under heterophase conditions [CH2Cl2-H2O; 1:1. 20mL]. Results show that: Polyalkylviologen radical (PRV^+) can be induced by LS component. When PRV-LS was reduced. The phase-transfer property of PRV^+ was observed. The complexes have good ability to induce the reduction of azobenzene.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, BENZENE AZO COMPOUNDS, OXIDATION, PROTON MAGNETIC RESONANCE SPECTROMETRY, PARAMAGNETIC RESONANCE, COMPLEX, VIOLOGENS, REDUCTION, INDUCTION, ELEMENTAL ANALYSIS

CLC Number:

O631.3

Cite this article

LIU FUTIAN;YU XIANDA;LI SHUBEN. Lauryl sulfate complexes and their application to electron- transfer catalyst[J]. Chin. J. Org. Chem., 1995, 15(6): 627-632.

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