Preparation of silica gel-supported methylammonium chlorochromate and its use in oxidation of alcohols

Chin. J. Org. Chem. ›› 1997, Vol. 17 ›› Issue (5): 450-453. Previous Articles Next Articles

Original Articles

氯铬酸甲铵/硅胶载体氧化剂的制备及其对醇的氧化研究

张贵生;石启增;陈密峰;蔡昆

河南师范大学化学系

发布日期:1997-10-25

Preparation of silica gel-supported methylammonium chlorochromate and its use in oxidation of alcohols

ZHANG GUISHENG;SHI QIZENG;CHEN MIFENG;CAI KUN

Published:1997-10-25

Abstract

Methylammonium chlorochromate adsorbed on silica gel is described and evaluated as a convenient reagent for efficient oxidation of a variety of primary and secondary alcohols. This reagent is easily prepared and very stable. Primary and secondary alcohols are oxidized by the reagent into corresponding carbonyl compounds in good yields. The oxidation of alcohols with the reagent can proceed easily in some solvents, the oxidation condition is mild and the products are unique and easily separated.

Key words: CHROMIC ACID P, CHLORIDE, OXIDANT, ALCOHOL, SILICA GEL, OXIDATION

CLC Number:

TQ42
O621

Cite this article

ZHANG GUISHENG;SHI QIZENG;CHEN MIFENG;CAI KUN. Preparation of silica gel-supported methylammonium chlorochromate and its use in oxidation of alcohols[J]. Chin. J. Org. Chem., 1997, 17(5): 450-453.

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氯铬酸甲铵/硅胶载体氧化剂的制备及其对醇的氧化研究

Preparation of silica gel-supported methylammonium chlorochromate and its use in oxidation of alcohols

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