Chin. J. Org. Chem. ›› 1997, Vol. 17 ›› Issue (5): 462-465. Previous Articles     Next Articles

Original Articles

复合还原剂NaBH~4/BiCl~3对α,β-不饱和腈的选择性还原

任平达;邵东;董庭威   

  1. 复旦大学化学系
  • 发布日期:1997-10-25

Selective reduction of α,β-unsaturated nitriles with combined reducing agent bismuth chloride/sodium borohydride

Ren Pingda;SHAO DONG;DONG TINGWEI   

  • Published:1997-10-25

Bismuth chloride/sodium borohydride reacts chemoselectively with α,β-unsaturated nitriles in 95% ethanol to give the corresponding saturated nitriles with good yields, the reduction mechanism is also discussed.

Key words: BISMUTH CHLORIDE, REACTION SELECTIVITY, SODIUM BOROHYDRIDE, REDUCTION REACTION, REDUCER, REACTION MECHANISM

CLC Number: