Chin. J. Org. Chem. ›› 1997, Vol. 17 ›› Issue (6): 520-523. Previous Articles     Next Articles

Original Articles

高序铜试剂在α-亚烷基-γ-丁内酯合成中的应用

陈祖兴;李焰;黄精美;徐章煌   

  1. 湖北大学化学系
  • 发布日期:1997-12-25

Application of higher order cuprate in synthesis of α-alkylene-γ-butyrolactones

CHEN ZUXING;LI YAN;HUANG JINGMEI;XU ZHANGHUANG   

  • Published:1997-12-25

A method to synthesis α-methylene-γ-butyrolactones was reported by the substituted (α-carbethoxyvinyl) cuprate intermediates, generated by the addition of higher order cuprate to acetylenic ester, traping with epoxides stereoselectively.

Key words: STEREOSELECTIVITY, CUPRON, EPOXIDE, UNSATURATED ESTERS, ORGANIC SYNTHESIS

CLC Number: