Synthesis and catalytic hydrosilylation activity of [60]  fullerene ethanolamine platinum complex

Chin. J. Org. Chem. ›› 1999, Vol. 19 ›› Issue (6): 600-605. Previous Articles Next Articles

Original Articles

C~6~0乙醇胺铂配合物的合成及其催化硅氢化性能

方鹏飞;陈远荫;王中华;卢秋生

武汉大学化学学院

发布日期:1999-12-25

Synthesis and catalytic hydrosilylation activity of [60] fullerene ethanolamine platinum complex

Fang Pengfei;Chen Yuanyin;Wang Zhonghua;Lu Qiusheng

Published:1999-12-25

Abstract

Fullerene ethanolamine platinum complex was prepared by reacting C~6~0 with ethanolamine, potassium chloroplatinite sequentialy. The complex was an effective catalyst for hydrosilylation of olefins with triethoxysilane. Interestingly, it exhibits nearly 100% regioselectivity for styrene α-adduct. The mechanism of hydrosilylation was also investigated.

Key words: FULLERENES, HYDROSILYLATION, COMPLEX COMPOUNDS, SELECTIVITY, PLATINUM COMPOUND, CATALYTIC MECHANISM, STYRENE

CLC Number:

O627
O631.3

Cite this article

Fang Pengfei;Chen Yuanyin;Wang Zhonghua;Lu Qiusheng. Synthesis and catalytic hydrosilylation activity of [60] fullerene ethanolamine platinum complex[J]. Chin. J. Org. Chem., 1999, 19(6): 600-605.

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C~6~0乙醇胺铂配合物的合成及其催化硅氢化性能

Synthesis and catalytic hydrosilylation activity of [60] fullerene ethanolamine platinum complex

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