Chin. J. Org. Chem. ›› 1999, Vol. 19 ›› Issue (6): 606-609. Previous Articles     Next Articles

Original Articles

使用苯基果糖硫苷给体立体专一地合成α-D-呋喃果糖苷

薛军;惠永正   

  1. 复旦大学化学系.上海(200433)
  • 发布日期:1999-12-25

Stereospecific synthesis of α-D-fructofuranosides using phenyl 2- thio-D-fructofuranosides

Xue Jun;Hui Yongzheng   

  1. Fudan Univ, Dept Chem.Shanghai(200433)
  • Published:1999-12-25

Benzoylated phenyl α- and β-2-thio-D-fructofuranosides were synthesized and coupled with protected sucrose acceptor to synthesize α-D-fructofuranoside-linkage stereospecifically by employing NIS/AgOTf as catalysts. The structures of all products were confirmed by ^1^3C NMR and ^1H NMR spectra.

Key words: FURAN P, GLYCOSYL, STEREO, SYNTHESIS, SPECIFICITY

CLC Number: