Study of electroorganic synthesis of 1, 4-bis[2-(3, 4,  5- trimethoxyphenyl)vinyl] benzene

Abstract

1, 4-bis[2-(3, 4, 5-trimethoxyphenyl)vinyl]benzene (abbreviated as HPV), one of the organic conducting materials, was synthesized by electro-reductively promoted Wittig reaction. A cylindrical sleeve cell with a diaphragm was used. The product was determined to be a light yellow mixture of three kinds of isomers of the title compound, 29.4% cis-cis, 44.7% cis-trans, 25.9% trans-trans isomers. The yield of the product was 92%, m.p. 103-155℃.

Key words: ELECTROCHEMICAL SYNTHESIS, METHOXY GROUP, BENZENE P, STYRYL GROUP, ORGANIC ELECTROLYTIC SYNTHESIS, CONDUCTING POLYMER, ELECTROLYTIC CELL

CLC Number:

O621
O646

Cite this article

Qiu Xiyuan. Study of electroorganic synthesis of 1, 4-bis[2-(3, 4, 5- trimethoxyphenyl)vinyl] benzene[J]. Chin. J. Org. Chem., 2000, 20(3): 348-351.

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电化学合成1, 4-双[2-(3, 4, 5-三甲氧基苯基)乙烯基]苯

Study of electroorganic synthesis of 1, 4-bis[2-(3, 4, 5- trimethoxyphenyl)vinyl] benzene

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