Synthesis and Thermochemical Properties of the Ternary Complex Ho(Et2dtc)3(phen)

Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (11): 1417-1422. Previous Articles Next Articles

三元配合物Ho(Et₂dtc)₃(phen)的合成及其热化学性质

朱丽, 焦宝娟, 帅琪, 杨旭武, 高胜利^*, 史启祯

西北大学化学系陕西省物理无机化学重点实验室西安 710069

收稿日期:2003-12-12 修回日期:2004-03-15 接受日期:2004-05-12 发布日期:2022-09-21
通讯作者: ^* E-mail: gaoshli@nwu.edu.cn
基金资助:
国家自然科学基金(No. 20171036)、陕西省教育厅专项基金(No. 01JK229)和西北大学重点基金(No. 02NW02)资助项目.

Synthesis and Thermochemical Properties of the Ternary Complex Ho(Et₂dtc)₃(phen)

ZHU Li, JIAO bao-Juan, SHUAI Qi, YANG Xu-Wu, GAO Sheng-Li^*, SHI Qi-Zhen

Department of Chemistry, Northwest University, Shaanxi Key Laboratory of Physico-inorganic Chemistry, Xi'an 710069

Received:2003-12-12 Revised:2004-03-15 Accepted:2004-05-12 Published:2022-09-21

Abstract

The ternary solid complex has been synthesized withsodium diethyldithiocarbamate (NaEt₂dtc), 1,10-phenanthroline (o-phen) and low hydrated holmium chloride in absolute ethanol by the improvement of the methods reported in reference. The title complex was identified as the general formula of Ho(Et₂dtc)₃(phen) by chemical and elemental analyses. IR spectrum of the complex showed that the Ho^3＋ is coordinated with six sulfur atomsof three NaEt₂dtc and two nitrogen atoms of phen. It was assumed that the coordination number of Ho^3＋ is eight. The enthalpy change of liquid-phase reaction [Δ_rH^Ө_m(l)] was determined as (-14.697±0.0376) kJ·mol^－1 at 298.15 K by a microcalorimeter, and the enthalpy change of the solid-phase reaction [Δ_rH^Ө_m(s)] was calculated as (117.504±0.619) kJ·mol^－1 on the basis of a thermochemical cycle. The thermokinetics of formation reaction was studied at different temperature by liquid-phase reaction.The constant-volume combustion energy of the complex, Δ_cU, was determined as (-18687.64±8.22) kJ·mol^－1 by a precise rotating-bomb calorimeter at 298.15 K. Its standard combustion enthalpy, Δ_cH^Ө_m, and standard enthalpy of formation, Δ_fH^Ө_m, were calculated as (-18706.85±8.22) and (-70.01±9.37) kJ·mol^－1, respectively.

Key words: Ho(Et₂dtc)₃(phen), synthesis, microcalorimeter, thermodynamic, constant-volume combustion energy, standard molar enthalpy of formation

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ZHU Li, JIAO bao-Juan, SHUAI Qi, YANG Xu-Wu, GAO Sheng-Li, SHI Qi-Zhen. Synthesis and Thermochemical Properties of the Ternary Complex Ho(Et₂dtc)₃(phen)[J]. Chinese Journal of Organic Chemistry, 2004, 24(11): 1417-1422.

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三元配合物Ho(Et₂dtc)₃(phen)的合成及其热化学性质

Synthesis and Thermochemical Properties of the Ternary Complex Ho(Et₂dtc)₃(phen)

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三元配合物Ho(Et2dtc)3(phen)的合成及其热化学性质