Study on Synthesis and Properties of Metallic Complexes of meso-Tetrakis(4-alkoxyphenyl)porphyrins (IV)

Chin. J. Org. Chem. ›› 2005, Vol. 25 ›› Issue (11): 1381-1385. Previous Articles Next Articles

Original Articles

meso-四(对烷氧苯基)卟啉金属配合物的合成和性能研究(IV)

宁静恒¹,2，赵鸿斌*^,1，周宁¹，顾峥¹，李纯清¹

(¹湘潭大学化学化工学院湘潭 411105)
(²长沙理工大学化学与环境工程系长沙 410076)

收稿日期:2005-04-08 修回日期:2005-05-17 发布日期:2005-10-30
通讯作者: 赵鸿斌

Study on Synthesis and Properties of Metallic Complexes of meso-Tetrakis(4-alkoxyphenyl)porphyrins (IV)

NING Jing-Heng¹,2,ZHAO Hong-Bin*^,1,ZHOU Ning¹,GU Zheng¹,LI Chun-Qing¹

(¹College of Chemistry amd Chemical Engineering, Xiangtan University, Xiangtan 411105)
(² Department of Chemistry and Environmental Engineering, Changsha University of Science and Technology,
Changsha 410076)

Received:2005-04-08 Revised:2005-05-17 Published:2005-10-30
Contact: ZHAO Hong-Bin

Abstract

meso-Tetrakis(4-alkoxyphenyl)porphyrins were generated by condensation of 4-alkoxybenzal- dehydes with pyrrole, followed by reaction with manganese acetate to form nine corresponding complexes. Molecular structures of all synthesized compounds were confirmed by IR, UV, ¹H NMR, MS spectra and elemental analysis. Characteristic spectrometric data of IR, UV, ¹H NMR related to their structures have been systematically analyzed. Differential scanning calorimetry and polarizing microscope were used to probe the liquid crystal properties of the serial complexes. Eight of the serial complexes were found to exhibit liquid crystal properties. The effects of alkoxy chains, metal ions of complexes and molecular space structure on liquid crystal properties have been investigated.

Key words: manganese complex of porphyrin, spectral analysis, liquid crystal property, synthesis

Cite this article

NING Jing-Heng^1,2,ZHAO Hong-Bin*^,1,ZHOU Ning,GU Zheng,LI Chun-Qing. Study on Synthesis and Properties of Metallic Complexes of meso-Tetrakis(4-alkoxyphenyl)porphyrins (IV)[J]. Chin. J. Org. Chem., 2005, 25(11): 1381-1385.

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meso-四(对烷氧苯基)卟啉金属配合物的合成和性能研究(IV)

Study on Synthesis and Properties of Metallic Complexes of meso-Tetrakis(4-alkoxyphenyl)porphyrins (IV)

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