Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (01): 120-122. Previous Articles     Next Articles

Reports

1-烷基-1'-乙酰基二茂铁的合成

王丽英,李保国*,石艳菊   

  1. (内蒙古大学化学化工学院 呼和浩特 010021)
  • 收稿日期:2004-12-28 修回日期:2005-07-18 发布日期:2005-12-31
  • 通讯作者: 李保国

Synthesis of 1-Alkyl-1'-acetylferrocenes

WANG Li-Ying,LI Bao-Guo*,SHI Yan-Ju   

  1. (College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot 010021)
  • Received:2004-12-28 Revised:2005-07-18 Published:2005-12-31
  • Contact: LI Bao-Guo

A novel synthetic method for 1-alkyl-1'-acetylferrocenes (CnH2n+1-Fc-COCH3, n=2~8, Fc=C5H4FeC5H4) was developed. Alkylferrocenoyl chlo-rides were added into the solution of sodium methoxylate with ethyl acetoacetate, then hydrolytic decar-boxylation led to 1-alkyl-1'-acetylferrocenes. The compositions and structures of all compounds were char-acterized by elemental analysis, IR and 1H NMR spectra.

Key words: 1-alkyl-1'-acetylferrocene, synthesis, alkylferrocenecarboxylic acid