Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (08): 1155-1163. Previous Articles    

Reports

胺作为配体在钯催化偶联反应中应用

谢叶香,李金恒*,尹笃林*   

  1. (湖南师范大学化学化工学院 化学生物学与中药分析教育部重点实验室 长沙 410081)
  • 收稿日期:2005-10-19 修回日期:2006-04-26 发布日期:2006-07-26
  • 通讯作者: 李金恒*,尹笃林*

Amines as the Ligands for Palladium-Catalyzed Coupling Reactions

XIE Ye-Xiang,LI Jin-Heng*,YIN Du-Lin*   

  1. (Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research, Ministry of Education,
    College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081)
  • Received:2005-10-19 Revised:2006-04-26 Published:2006-07-26
  • Contact: LI Jin-Heng*,YIN Du-Lin*

Progress of our group and the other groups’ recent work in the field of palladium-catalyzed coupling reactions using amine as the ancillary ligands is summarized. The coupling reactions using the combination of palladium and amines as the catalytic system include the Suzuki-Miyaura cross-coupling reaction, Sonogashira cross-coupling reaction, Stille cross-coupling reaction, Hiyama cross-coupling reaction and Heck reaction. The results show that amine could be used as the inexpensive and highly efficient ligands to promote the palladium-catalyzed coupling reactions.

Key words: ligand, coupling reaction, palladium, amine