Synthesis and Characterization of Di(2-pyridyloxy) Axially Substituted Tetra-(α-pentyloxy)tin(IV) Phthalocyanine

Abstract

3-Pentoxyphthalonitrile (1) was synthesized by using 3-nitrophthalonitrile as raw material. Dichloro-tetra-(α-pentyloxy)tin(IV) phthalocyanine (2) was prepared by condensation of 1 with TiCl₄in 1-chloronaphthalene. A novel axially substituted tin phthalocyanine, namely di(2-pyridyloxy) axially substituted tetra-(α-pentyloxy)tin(IV) phthalocyanine (3) was synthesized by reaction of 2 with 2-hydroxypyridine. The above complexes were characterized by the elemental analysis, UV/Vis, IR, MS, ¹H NMR spectra as well as fluorescence spectroscopy.

Key words: tin phthalocyanine, synthesis, characterization, axially substituted

Cite this article

PENG Yi-Ru*^,a,b,CAO Yu-Hong,b,HUANG Feng-Hua,b
WEN Jia-Bao,b,HUANG Xiao-Xia,b . Synthesis and Characterization of Di(2-pyridyloxy) Axially Substituted Tetra-(α-pentyloxy)tin(IV) Phthalocyanine[J]. Chin. J. Org. Chem., 2008, 28(05): 910-913.

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