Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (07): 1169-1180. Previous Articles     Next Articles

Review

轴不稳定手性配体的开发及其在不对称催化反应中的应用

戴轶俊 ; 杨国强; 张勇健 ; 王飞军; 张万斌*   

  1. (上海交通大学化学化工学院 上海 200240)
  • 收稿日期:2007-09-05 修回日期:2007-12-04 发布日期:2008-07-28
  • 通讯作者: 张万斌

Development of Axial-unfixed (Tropos) Ligands and Their Applications to Asymmetric Catalytic Reactions

DAI, Yi-Jun; YANG, Guo-Qiang ; ZHANG, Yong-Jian; WANG, Fei-Jun ; ZHANG, Wan-Bin*
  

  1. (School of Chemistry & Chemical Technology, Shanghai Jiaotong University, Shanghai 200240)
  • Received:2007-09-05 Revised:2007-12-04 Published:2008-07-28
  • Contact: ZHANG, Wan-Bin

Tropos ligands, compared with traditional atropos ligands, have unique characteristics. Here, the development of several major types of tropos ligands, including oxazoline, biphosphine, monophosphine, bihydroxyl and N—O ligands, and their applications to asymmetric catalysis are reviewed.

Key words: axial-unfixed ligand, asymmetric catalysis, axial chirality