Progress in Preparation of Chiral NHC-Metal Complexes and Their Use as Catalysts in Asymmetric Reactions

Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (10): 1499-1507. Previous Articles Next Articles

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手性氮杂卡宾金属络合物的合成及其在不对称催化反应中的应用

古丽娜^a,b 祝冠彬^a宋海斌^*,a 自国甫^*,b

^a南开大学元素有机化学国家重点实验室天津 300071, ^b北京师范大学化学学院北京 100875

收稿日期:2009-01-07 修回日期:2009-02-17 发布日期:2009-03-09

Progress in Preparation of Chiral NHC-Metal Complexes and Their Use as Catalysts in Asymmetric Reactions

Gu, Lina ^a,b Zhu, Guanbin^aSong, Haibin^*,a Zi, Guofu^*,b

^aState Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071, ^b College of Chemistry, Beijing Normal University, Beijing 100875

Received:2009-01-07 Revised:2009-02-17 Published:2009-03-09

Abstract

Organometallic complexes with chiral nitrogen-heterocyclic-carbenes (NHC) have been extensively used in catalytic reactions with excellent catalytic activity. This review summarizes the progress in the preparation of the chiral NHC-metal complexes and their use as catalysts in asymmetric reactions such as asymmetric 1,4-addition of α,β-unsaturated ketones, hydrosilylation of ketones, hydrogenation of olefins and olefin metathesis reaction, etc.

Key words: chiral NHC-metal complex, synthesis, enantioselective catalysis

Cite this article

GU Li-Na, CHU Guan-Ban, SONG Hai-Bin, ZI Guo-Fu-. Progress in Preparation of Chiral NHC-Metal Complexes and Their Use as Catalysts in Asymmetric Reactions[J]. Chin. J. Org. Chem., 2009, 29(10): 1499-1507.

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手性氮杂卡宾金属络合物的合成及其在不对称催化反应中的应用

Progress in Preparation of Chiral NHC-Metal Complexes and Their Use as Catalysts in Asymmetric Reactions

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