Photoinduced Single Electron Transfer Cyclization Reactions of N-(Amidosilane terminated polybenzylglycine peptide chain)phthalimide

Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (06): 860-864. Previous Articles Next Articles

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N-(末端三甲基硅苄基甘氨酸肽链)邻苯二甲酰亚胺的光诱导单电子转移成环反应

金英学*，谭广慧，赵俊明，张鹏，王丙南，郑鹏

哈尔滨师范大学化学化工学院哈尔滨 150025

收稿日期:2009-08-28 修回日期:2009-11-19 发布日期:2010-01-15
通讯作者: 金英学 E-mail:yenghak@hrbnu.edu.cn

Photoinduced Single Electron Transfer Cyclization Reactions of N-(Amidosilane terminated polybenzylglycine peptide chain)phthalimide

JIN Ying-Xue, TAN Guang-Hui, ZHAO Jun-Ming, ZHANG Peng, WANG Bing-nan, ZHENG Peng

College of Chemistry & Chemical Engineering, Harbin Normal University, Harbin 150025

Received:2009-08-28 Revised:2009-11-19 Published:2010-01-15

Abstract

Benzylglycine was used as starting material for the synthesis of N-(amidosilane teminated polybenzylglycine peptide chain)phthalimide (1). Irradiating methanol solution containing 1 is observed to promote formation of biradical 10. Then the biradical 10 copulates to give cyclopolyglypeptides 2 in high yield and high selectivity. The structures of all the new compounds were characterized by MS and NMR techniques.

Key words: photoinduced, single electro transfer, cyclic peptide compound, synthesis

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JIN Ying-Xue, TAN Guang-Hui, ZHAO Jun-Ming, ZHANG Peng, WANG Bing-nan, ZHENG Peng. Photoinduced Single Electron Transfer Cyclization Reactions of N-(Amidosilane terminated polybenzylglycine peptide chain)phthalimide[J]. Chin. J. Org. Chem., 2010, 30(06): 860-864.

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N-(末端三甲基硅苄基甘氨酸肽链)邻苯二甲酰亚胺的光诱导单电子转移成环反应

Photoinduced Single Electron Transfer Cyclization Reactions of N-(Amidosilane terminated polybenzylglycine peptide chain)phthalimide

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