Synthesis, Characterization and Performances of 7-Amino-6-nitrobenzodifuroxans

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (05): 701-707. Previous Articles Next Articles

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7-氨基-6-硝基苯并二氧化噁二唑(呋咱)的合成、结构表征与性能研究

霍欢*，王伯周，周诚，周彦水，罗义芬

(西安近代化学研究所西安 710065)

收稿日期:2010-05-19 修回日期:2010-09-24 发布日期:2010-12-30
通讯作者: 霍欢 E-mail:huohuan-234@163.com
基金资助:
973子专题呋咱成环反应机理研究

Synthesis, Characterization and Performances of 7-Amino-6-nitrobenzodifuroxans

HUO Huan, WANG Bo-Zhou, ZHOU Cheng, ZHOU Yan-Shui, LUO Yi-Fen

(Xian Modern Chemistry Research Institute, Xian 710065)

Received:2010-05-19 Revised:2010-09-24 Published:2010-12-30

7-Amino-6-nitrobenzodifuroxan (ANBDF) was synthesized from 1,3,5-trinitro- 2,4-dichlorobenzene through azidation, denitrogenation and vicarious nucleophilic substitution (VNS) reactions. ANBDF and the intermediate products were characterized by IR, NMR, MS techniques and elemental analysis. The optimal conditions of VNS were discussed and confirmed. The best conditions were obtained as follows: the VNS reagent is NH₂OH•HCl, the reaction time is 5 h, the reaction temperature is 20～40 ℃, and the overall yield is 51.0%. The results show that ANBDF had favorable mechanical sensitivities and thermal stability. DSC and TG-DTG measurements indicate that there were two decomposition processes of ANBDF at 194.1 and 200.2 ℃.

Key words: synthesis, 7-amino-6-nitrobenzodifuroxan, VNS, performance

CLC Number:

TQ 560.72

Cite this article

HUO Huan, WANG Bo-Zhou, ZHOU Cheng, ZHOU Yan-Shui, LUO Yi-Fen. Synthesis, Characterization and Performances of 7-Amino-6-nitrobenzodifuroxans[J]. Chin. J. Org. Chem., 2011, 31(05): 701-707.

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7-氨基-6-硝基苯并二氧化噁二唑(呋咱)的合成、结构表征与性能研究

Synthesis, Characterization and Performances of 7-Amino-6-nitrobenzodifuroxans

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