Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (10): 1538-1552. Previous Articles     Next Articles

Reviews

镍催化芳基-芳基交叉偶联反应的配体研究新进展

李永清,曹育才*,叶晓峰,周慧   

  1. (上海化工研究院 上海 200062)
  • 收稿日期:2011-01-07 修回日期:2011-02-28 发布日期:2011-03-04
  • 通讯作者: 鲍小平 E-mail:baoxp_1980@yahoo.com.cn

New Progress in Nickel-Catalyzed Aryl-Aryl Cross-Coupling Reac-tions: A Ligand Survey

LI Yong-Qing, CAO Yu-Cai, YE Xiao-Feng, ZHOU Hui   

  1. (Shanghai Research Institute of Chemical Industry, Shanghai 200062)
  • Received:2011-01-07 Revised:2011-02-28 Published:2011-03-04

Biaryls widely exist in natural products, pharmaceuticals and various photoelectricity materials. Remarkable progress of cross-couplings has been achieved since the 70s of 20th century using a few transition metals for the production of biaryls. Particular attentions are being focused on ligands, substrates and assistant tech-niques. Nickel-catalyzed aryl-aryl cross-coupling reactions are reviewed from the point of ligands.

Key words: nickel, transition metal catalysis, ligand, biaryl, cross coupling