Chin. J. Org. Chem. ›› 1999, Vol. 19 ›› Issue (2): 141-146. Previous Articles     Next Articles

Original Articles

聚合物支载溴酸根的氧化性能研究

杨桂春;陈祖兴;黄锦霞;陈家威;石从云   

  1. 湖北大学化学与材料科学学院
  • 发布日期:1999-04-25

Study on polymer-supported bromate ion oxidizer

Yang Guichun;Chen Zuxing;Huang Jinxia;Chen Jiawei;Shi Congyun   

  • Published:1999-04-25

Polymer-supported bromate ion oxidizer was prepared from strong basic ion-exchange resin with sodium bromate. In the presence of 40% HBr or AlCl~3 or NaHSO~3, the primary alcohols and simple ethers were readily oxidized to esters; secondary alcohols to ketones; α, ω- diols and cyclic thers to lactones; thoils and selenols to the corresponding disulfides and diselenides with good to excellient yields respectively, by the polymer-supported bromate ion oxidizer.

Key words: HYDROSULFIDE OF SODIUM, OXIDANT, ESTERS, BROMIC ACID, KETONE, ION EXCHANGE RESINS, ALUMINIUM CHLORIDE, ALCOHOL, ETHER, HIGHPOLYMER

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