Chin. J. Org. Chem. ›› 1993, Vol. 13 ›› Issue (5): 545-548. Previous Articles     Next Articles

Original Articles

相转移催化下二醇类及肟类的选择性间接电氧化

李伟;王桂兰;张贵生;李志鸿;蔡Kun   

  1. 河南师范大学化学系.新湘(453002)
  • 发布日期:1993-10-25

Silective electrical oxidation of dihydric alcohols and oximes under phase transfer catalysis

Li Wei;Wang Guilan;Zhang Guisheng;Li Zhihong;CAI Ku   

  1. Henan Normal Univ, Dept Chem.Xinxiang(453002)
  • Published:1993-10-25

The Cr(VI)/Cr(III) as an indirect redox system to oxidize dihydric alcohols containing both a benzylic and a sated hykroxy group, is studied by means of indirect electrical oxidation under phase transfer catalysis. The experimental results show that it could selectively oxidize the benzylic hydroxy group without affecting the primary or secondary aliphatic hydroxy group. Under the similar conditions, various oximes were also selectively oxidized to the corresponding carbonyl compounds.

Key words: OXIME, ELECTROOXIDATION, PHASE TRANSFER CATALYSIS

CLC Number: