Chin. J. Org. Chem. ›› 1993, Vol. 13 ›› Issue (4): 434-437. Previous Articles     Next Articles

Original Articles

手性位移试剂Eu(dcm)~3的一个改进合成方法

潘显道;尤田耙;蒋祥玉;伍越环;沈晓明   

  1. 中国科学技术大学化学系.合肥(230026)
  • 发布日期:1993-08-25

A facile route for synthesis of chiral shift reagent Eu(dcm)~3

Pan Xiandao;You Tianpa;Jiang Xiangyu;Wu Yuehuan;Shen Xiaoming   

  1. Univ Sci & Technol China, Dept Chem.Hefei(230026)
  • Published:1993-08-25

A facile method for synthesis of tris[d, d-dicampholylmethanato] europium(III)---one of the most effective Chiral Shift Reagent was reported. Where the ligant d, d-dicampholylmethene [H(dcm)] has been prepared under mild conditions by using organic magnesium regeants instead of organiclithium reagents in high yield.

Key words: SHIFT REAGENT, SYNTHESIS, IMPROVEMENT, CHIRAL REAGENT

CLC Number: