One-Step Synthesis of Fluorene or Phenanthrene Derivatives via the Reaction of Arylaldehyde and Malononitrile with 2-(1,2-Dihydroinden- 3-ylidene)malononitrile or 2-(2,3-Dihydronaphthalen-4(1H)-ylidene)- malononitrile Catalyzed by KF/Al2O3 in Ethyl Alcohol

Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (01): 108-111. Previous Articles Next Articles

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KF/Al2O3催化下由芳醛、丙二腈和2-(1,2-二氢-3-亚茚基)丙二腈或2-(2,3-二氢-4H-亚萘基)丙二腈一步合成芴或菲衍生物

梁静^*,a ; 张梅梅^b; 魏贤勇^a ; 宗志敏^a ; 王香善^b

(a中国矿业大学化工学院徐州221116)
(b徐州师范大学化学系徐州221116)

收稿日期:2007-12-04 修回日期:2008-07-10 发布日期:2009-01-20
通讯作者: Liang, Jing

One-Step Synthesis of Fluorene or Phenanthrene Derivatives via the Reaction of Arylaldehyde and Malononitrile with 2-(1,2-Dihydroinden- 3-ylidene)malononitrile or 2-(2,3-Dihydronaphthalen-4(1H)-ylidene)- malononitrile Catalyzed by KF/Al2O3 in Ethyl Alcohol

Liang, Jing^*,a ; Zhang, Meimei ^b; Wei, Xianyong^a ; Zong, Zhimin^a;
Wang, Xiangshan^b

(a School of Chemical Engineering, China University of Mining and Technology, Xuzhou 221116)
(b Department of Chemistry, Xuzhou Normal University, Xuzhou 221116)

Received:2007-12-04 Revised:2008-07-10 Published:2009-01-20
Contact: Liang, Jing

Abstract

A series of fluorene or phenanthrene derivatives were synthesized from arylaldehyde, malononitrile and 2-(1,2-dihydroinden-3-ylidene)malononitrile or 2-(2,3-dihydronaphthalen-4(1H)-ylidene)-malono-
nitrile catalyzed by KF/Al2O3 at 80 ℃ in ethyl alcohol. This method has the advantages of mild reaction conditions, high yields (72%～88%) and easy operation. The structures of the products were characterized by IR, 1H NMR spectra and elemental analyses.

Key words: phenanthrene, KF/Al2O3, synthesis, fluorene

Cite this article

Liang, Jing^*,a ; Zhang, Meimei ^b; Wei, Xianyong^a ; Zong, Zhimin^a;
Wang, Xiangshan^b
. One-Step Synthesis of Fluorene or Phenanthrene Derivatives via the Reaction of Arylaldehyde and Malononitrile with 2-(1,2-Dihydroinden- 3-ylidene)malononitrile or 2-(2,3-Dihydronaphthalen-4(1H)-ylidene)- malononitrile Catalyzed by KF/Al2O3 in Ethyl Alcohol[J]. Chin. J. Org. Chem., 2009, 29(01): 108-111.

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KF/Al2O3催化下由芳醛、丙二腈和2-(1,2-二氢-3-亚茚基)丙二腈或2-(2,3-二氢-4H-亚萘基)丙二腈一步合成芴或菲衍生物

One-Step Synthesis of Fluorene or Phenanthrene Derivatives via the Reaction of Arylaldehyde and Malononitrile with 2-(1,2-Dihydroinden- 3-ylidene)malononitrile or 2-(2,3-Dihydronaphthalen-4(1H)-ylidene)- malononitrile Catalyzed by KF/Al2O3 in Ethyl Alcohol

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