Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (04): 517-527. Previous Articles     Next Articles

Review

螺共轭效应及其应用

魏荣宝*; 张大为 ; 刘 博; 刘 洋; 李文丽 ; 贾辰熙   

  1. (天津理工大学化学化工学院 天津 300191)
  • 收稿日期:1900-01-01 修回日期:1900-01-01 发布日期:2009-04-20
  • 通讯作者: 魏荣宝

Spiroconjugation Effect and Application

Wei, Rongbao* ; Zhang, Dawei ; Liu, Bo ; Liu, Yang; Li, Wenli ; Jia, Chenxi   

  1. (College of Chemistry & Chemical Engineering, Tianjin University of Technology, Tianjin 300191)
  • Received:1900-01-01 Revised:1900-01-01 Published:2009-04-20
  • Contact: Wei, Rongbao

The expression spiroconjugation was introduced in 1967 by Simmons and Fukunaga and has drawn great attention because of its unique steric electric effect. Spiroconjugation effect has an important value in organic light-emitting materials, light changed color materials, nonlinear optical materials, charge-transfer dyes and organic conductors. In this review, the progress in theory and application during recent 40 years has been described. The potential application of spiroconjugation together with some novel ideas is supplied.

Key words: spiroconjugation, spiro compound, electronic spectra, application