Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (3): 298-304. Previous Articles     Next Articles

一种新的催化方法:微波辐射-酶耦合成催化有机合成

蔡汉成;方云;夏咏梅;蔡琨   

  1. 江南大学化学与材料工程学院
  • 发布日期:2003-03-25

A Novel Catalytic Technique: Microwave Irradiation-Enzyme Coupling Catalysis

Gai Hancheng;Fang Yun;Xia YonMei;Cai Kunk   

  1. School of chemical &Material Engineering,Southern Yangtze University
  • Published:2003-03-25

Microwave irradiation and enzymatic catalysis are two powerful tools in modern organic syntheses. A new trend in catalyzing organic syntheses is to utilize these two means simultaneously, which can be called microwave irradiation-enzyme coupling catalysis (MEECC). MIECC technique can be divided into two categories such as enzymatic synthesis under microwave irradiation in non/micro-aqueous media (wet method) and without media (dry method) . The recent progress in this research field is reviewed and the typical MIECC reactions are highlighted. The mechanism of MIECC, especially the microwave-induced "athermal action" in bio-catalysis systems is briefly discussed theoretically. The potential application of MIECC is prospected.

Key words: MICROWAVE RADIATION;ENZYME;COUPLING REACTION;CATALYTIC REACTION, REACTION MECHANISM

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