Advances in Synthesis and Research of Macrocyclic Compounds Containing Tetrathiafulvalene

Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (10): 1220-1227. Previous Articles Next Articles

Review

含四硫富瓦烯大环化合物的合成与研究进展

李洪启*^,a，宋燕西^b，彭家建^c，邱化玉^c

(^a东华大学化学与化工学院上海 201620)
(^b东华大学环境科学与工程学院上海 201620)
(^c杭州师范学院有机硅化学及材料技术重点实验室杭州 310012)

收稿日期:2006-12-11 修回日期:2007-01-17 发布日期:2007-09-28
通讯作者: 李洪启

Advances in Synthesis and Research of Macrocyclic Compounds Containing Tetrathiafulvalene

LI Hong-Qi*^,a,SONG Yan-Xi^b,PENG Jia-Jian^c,QIU Hua-Yu^c

(^a College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620)
(^b College of Environmental Science and Engineering, Donghua Univer-sity, Shanghai 201620)
(^c Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education,
Hangzhou Teachers College, Hangzhou 310012)

Received:2006-12-11 Revised:2007-01-17 Published:2007-09-28
Contact: LI Hong-Qi

Abstract

Classification of macrocyclic compounds containing tetrathiafulvalene is introduced briefly. The synthetic methods of macrocyclic compounds containing tetrathiafulvalene are outlined, which mainly include the coupling reaction of a macrocyclic compound containing a 1,3-dithiole-2-thione unit mediated by trialkyl phosphite and reactions between a well-designed tetrathiafulvalene functionalized by cyanoethylthio groups or other substituents and an oligo (ethylene glycol) dihalide. The latest advances in research on electrochemical properties and applications to molecular recognition of macrocyclic compounds containing tetrathiafulvalene are reviewed. The development trends in research on such macrocyclic compounds containing tetrathiafulvalene are proposed.

Key words: macrocyclic compound, synthesis, electrochemical property, molecular recognition, tetrathiafulvalene

Cite this article

LI Hong-Qi*^,a,SONG Yan-Xi^b,PENG Jia-Jian^c,QIU Hua-Yu^c. Advances in Synthesis and Research of Macrocyclic Compounds Containing Tetrathiafulvalene[J]. Chin. J. Org. Chem., 2007, 27(10): 1220-1227.

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含四硫富瓦烯大环化合物的合成与研究进展

Advances in Synthesis and Research of Macrocyclic Compounds Containing Tetrathiafulvalene

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